42.0
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 17.05.2016 *
Version number 3
Revision: 17.05.2016
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: Unifix S3 (Powder) · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Tile adhesive · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Product Safety Department Tel: ++49 (0)5231/953-193 Fax: ++49 (0)5231/953-106 email: guido.herfort@schomburg.de SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Eye Dam. 1 H318 Causes serious eye damage. GHS07 Skin Irrit. 2 H315 Causes skin irritation. STOT SE 3 H335 May cause respiratory irritation. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05, GHS07 · Signal word Danger · Hazard-determining components of labelling: Cement, portland, chemicals calcium dihydroxide · Hazard statements H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. (Contd. on page 2) GB
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 17.05.2016
Trade name: Unifix S3 (Powder) (Contd. of page 1)
P304+P340 P405 P501
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/ international regulations.
· 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Product based on cement and mineral filler. · Dangerous components: CAS: 65997-15-1 Cement, portland, chemicals EINECS: 266-043-4 Eye Dam. 1, H318; Skin Irrit. 2, H315; STOT SE 3, H335 CAS: 1305-62-0 calcium dihydroxide EINECS: 215-137-3 Eye Dam. 1, H318;
25-50% < 1%
Skin Irrit. 2, H315; STOT SE 3, H335
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. · After inhalation Supply fresh air; consult doctor in case of symptoms. · After skin contact Instantly wash with water and soap and rinse thoroughly. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. · After swallowing Rinse out mouth and then drink plenty of water. In case of persistent symptoms consult doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents Use fire fighting measures that suit the environment. · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: No special measures required. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Wear protective clothing. Avoid causing dust. Avoid eye- and skin contact. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents (Contd. on page 3) GB
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Trade name: Unifix S3 (Powder) (Contd. of page 2)
Pick up the product mechanically, avoid dust formation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. *
SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Protect against wetness and water. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available.
*
SECTION 8: Exposure controls/personal protection · Additional information about design of technical systems: It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 65997-15-1 Cement, portland, chemicals (25-50%) OES Long-term value: 10* 4** mg/m³ *total inhalable dust **respirable dust · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Wash hands during breaks and at the end of the work. Vacuum clean contaminated clothing. Do not blow or brush off contamination. Avoid contact with the eyes and skin. · Breathing equipment: Use respiratory protective equipment at formation of dust. · Protection of hands: Hand Protection: Nitril-rubber-latex-gloves. · Material of gloves Butyl rubber II R: Thickness ≥ 0,5mm; Break through time ≥ 480 min · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Safety glasses · Body protection: Protective work clothing.
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid (Contd. on page 4) GB
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Trade name: Unifix S3 (Powder) (Contd. of page 3)
Colour: · Smell:
Grey Characteristic
· Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined · Flash point:
Not applicable
· Self-inflammability:
Product is not selfigniting.
· Danger of explosion:
Product is not explosive.
· Density at 20 °C
1,445 g/cm³
· Solubility in / Miscibility with Water: Fully miscible · 9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known *
SECTION 11: Toxicological information · 11.1 Information on toxicological effects · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 1305-62-0 calcium dihydroxide Oral LD50 7340 mg/kg (rats) 544-17-2 Calciumformiat Oral LD50 3050 mg/kg (rats) Dermal LD50 >2000 mg/kg (rats) Inhalative LC50/4 h >0.67 mg/l (rats) · Primary irritant effect: · Skin corrosion/irritation Causes skin irritation. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure May cause respiratory irritation. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. GB
(Contd. on page 5)
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Trade name: Unifix S3 (Powder) (Contd. of page 4)
SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 544-17-2 Calciumformiat LC 0 (96h) 1000 mg/l (Brachydanio rerio) EC50 (48h) >1000 mg/l (Daphnia magna) EC50 >1000 mg/l (bacterial toxicity) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Other adverse effects No further relevant information available. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · European waste catalogue 10 00 00 Inorganic wastes from thermal processes 10 12 00 wastes from manufacture of ceramic goods, bricks, tiles and constructions products 10 12 03 other particulates and dust · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. SECTION 14: Transport information · 14.1 UN-Number · ADR
Void
· 14.2 UN proper shipping name · ADR
· 14.3 Transport hazard class(es) · ADR · Class
· 14.4 Packing group · ADR
· 14.5 Environmental hazards:
Not applicable.
· 14.6 Special precautions for user
Not applicable. (Contd. on page 6) GB
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Trade name: Unifix S3 (Powder) (Contd. of page 5)
· 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. · Transport/Additional information:
Not dangerous according to the above specifications.
· Number/Letter:
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · National regulations · Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H318 Causes serious eye damage. H335 May cause respiratory irritation. · Department issuing data specification sheet: Environment protection department. · Contact: Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
· * Data compared to the previous version altered. GB