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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 27.09.2023
Version number 1
Revision: 27.09.2023
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: MONOFLEX-S2 · 1.2 Relevant identified uses of the substance or mixture and uses advised against · Sector of Use SU19 Building and construction work · Application of the substance / the mixture Tile adhesive · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-Mail: SDB@schomburg.de SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 corrosion Eye Dam. 1 H318 Causes serious eye damage.
Skin Irrit. 2 H315 Causes skin irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS05, GHS07 · Signal word Danger · Hazard-determining components of labelling: calcium sulfoaluminate cement · Hazard statements H315 Causes skin irritation. H318 Causes serious eye damage. (Contd. on page 2) GB
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Trade name: MONOFLEX-S2 (Contd. of page 1)
H317 May cause an allergic skin reaction. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P280 Wear protective gloves / eye protection / face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Product based on cement and mineral filler. · Dangerous components: EC number: 934-133-9 calcium sulfoaluminate cement Eye Dam. 1, H318; Skin Irrit. 2, H315; Skin Sens. 1, H317; STOT SE 3, H335 · Additional information For the wording of the listed hazard phrases refer to section 16.
10-25%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact Instantly wash with water and soap and rinse thoroughly. Wash with water and soap. After contact, clean the skin mechanical and rinse with water and soap. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing Do not induce vomiting; instantly call for medical help. Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. (Contd. on page 3) GB
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Trade name: MONOFLEX-S2 (Contd. of page 2)
· 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. The product may not leak out in sewerage system, stretch of water or soil. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. Pick up the product mechanically, avoid dust formation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of dust. Keep away from children. · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: None. · 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 1317-65-3 Calciumcarbonat (25-50%) WEL Long-term value: 10* 4** mg/m³ *inhalable dust; **respirable (Contd. on page 4) GB
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Trade name: MONOFLEX-S2 (Contd. of page 3)
· Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Instantly remove any soiled and impregnated garments. Vacuum clean contaminated clothing. Do not blow or brush off contamination. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. · Hand protection Do not reuse one-way-gloves Hand Protection: Nitril-rubber-latex-gloves. In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Suitable protective gloves have been determined for activities with products containing cement (GISCODES ZP1). Suitable are e.g: Ampri: SolidSafety Cut 081101 / SolidSafety Tough 081201 / SolidSafetyTough Dots 081202 Ansell: Flexitril L27 / Fleximax 27 or 35 / Hylite / Nitrotough N210 / Sol-Knit KCL: Sahara / Gobi / Nitex MAPA: Duo-Mix 405 / Enduro 328 / Stansolv AK 22 / Titanlite 397 / Titansuperlite UVEX: uvex Profi Ergo XG 20 / uvex phynomic pro The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye/face protection Tightly sealed safety glasses. · Body protection: Protective work clothing. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Solid material. · Colour: grey · Smell: Characteristic · Odour threshold: Not determined. · Melting point/freezing point: >1,000 °C · Boiling point or initial boiling point and boiling range not apply (Contd. on page 5) GB
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Trade name: MONOFLEX-S2 (Contd. of page 4)
· Flammability · Lower and upper explosion limit · Lower: · Upper: · Flash point: · Decomposition temperature: · pH at 20 °C · Viscosity: · Kinematic viscosity · dynamic: · Solubility · Water: · Partition coefficient n-octanol/water (log value) · Steam pressure: · Density and/or relative density · Density · Relative density · Vapour density
Not determined. Not determined. Not determined. Not applicable Not determined. 11.4 (1%) Not applicable. Not applicable. miscible Not determined. Not applicable. bulk density Not determined. Not applicable.
· 9.2 Other information · Appearance: · Form: Powder · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Change in condition · Evaporation rate Not applicable. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. (Contd. on page 6) GB
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Trade name: MONOFLEX-S2 (Contd. of page 5)
· 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 1317-65-3 Calciumcarbonat Oral LD50 >5,000 mg/kg (rats) · Skin corrosion/irritation Causes skin irritation. · Serious eye damage/irritation Causes serious eye damage. · Respiratory or skin sensitisation May cause an allergic skin reaction. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 1317-65-3 Calciumcarbonat LC50/96h >10,000 mg/l (rainbow trout) EC50 (48h) >1,000 mg/l (Daphnia magna) EC50 289 mg/l /72h (Desmodesmus subspicatus) NOEC 75 mg/l /72h (Desmodesmus subspicatus) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. Rinse off of bigger amounts into drains or the aquatic environment may lead to increased pH-values. A high pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably reduced, so that after the use of the product the aqueous waste, emptied into drains, is only low water-dangerous. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. (Contd. on page 7) GB
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Trade name: MONOFLEX-S2 (Contd. of page 6)
· Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards:
Not applicable.
· 14.6 Special precautions for user
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. · Department issuing data specification sheet: Department EHS (Environment-Health-Safety) Environment protection department. · Contact: Department EHS (Environment-Health-Safety) · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent (Contd. on page 8) GB
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Trade name: MONOFLEX-S2 (Contd. of page 7) LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Skin Sens. 1: Skin sensitisation – Category 1 STOT SE 3: Specific target organ toxicity (single exposure) – Category 3 GB