59.1.3
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Safety data sheet according to UK REACH Printing date 24.07.2024 *
Version number 6 (replaces version 5)
Revision: 24.07.2024
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: CRISTALLFUGE-EPOX (C-Komp.) jasmin, pergamon, silbergrau, weiß · UFI: RGK9-39P1-900D-7ET0 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Mineral based Aggregate · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 health hazard Carc. 2 H351 Suspected of causing cancer. Route of exposure: Inhalation. STOT RE 2 H373 May cause damage to the lung through prolonged or repeated exposure. Route of exposure: Inhalation. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS08 · Signal word Warning · Hazard-determining components of labelling: cristobalite titanium dioxide · Hazard statements H351 Suspected of causing cancer. Route of exposure: Inhalation. H373 May cause damage to the lung through prolonged or repeated exposure. Route of exposure: Inhalation. · Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. (Contd. on page 2) GB
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Safety data sheet according to UK REACH Printing date 24.07.2024
Trade name: CRISTALLFUGE-EPOX (C-Komp.) jasmin, pergamon, silbergrau, weiß (Contd. of page 1)
P280
Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. P308+P313 IF exposed or concerned: Get medical advice/attention. P314 Get medical advice/attention if you feel unwell. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Additional information: EUH208 Contains N,N'-ethane-1,2-diylbis(12-hydroxyoctadecan-1-amide). May produce an allergic reaction. EUH212 Warning! Hazardous respirable dust may be formed when used. Do not breathe dust. · 2.3 Other hazards The product develops an alkaline pH value with moisture and can then have an irritating effect. Wear protective gloves. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: compound of mineral lightfiller and additives Product based on cement and mineral filler. · Dangerous components: CAS: 14464-46-1 EINECS: 238-455-4
cristobalite STOT RE 2, H373
10-25%
CAS: 13463-67-7 titanium dioxide EINECS: 236-675-5 Carc. 2, H351 Index number: 022-006-00-2
2.5-10%
CAS: 123-26-2 N,N'-ethane-1,2-diylbis(12-hydroxyoctadecan-1-amide) EINECS: 204-613-6 Skin Sens. 1B, H317; Aquatic Chronic 3, H412 · Additional information For the wording of the listed hazard phrases refer to section 16.
<0.5%
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Instantly remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact In case of contact with skin, remove mechanically, wash thoroughly with plenty of soap and water. Instantly wash with water and soap and rinse thoroughly. Instantly rinse with water. · After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. (Contd. on page 3) GB
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Trade name: CRISTALLFUGE-EPOX (C-Komp.) jasmin, pergamon, silbergrau, weiß (Contd. of page 2)
· After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents Use fire fighting measures that suit the environment. · For safety reasons unsuitable extinguishing agents Cement · 5.2 Special hazards arising from the substance or mixture No further relevant information available. · 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Ensure adequate ventilation. Pick up the product mechanically, avoid dust formation. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Prevent formation of dust. Keep out of the reach of children · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. · 7.3 Specific end use(s) No further relevant information available. GB
(Contd. on page 4)
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Trade name: CRISTALLFUGE-EPOX (C-Komp.) jasmin, pergamon, silbergrau, weiß (Contd. of page 3)
*
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: 1344-28-1 aluminium oxide (2.5-10%) WEL Long-term value: 10* 4** mg/m³ *inhalable dust **respirable dust 13463-67-7 titanium dioxide (2.5-10%) WEL Long-term value: 10* 4** mg/m³ *total inhalable **respirable · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Vacuum clean contaminated clothing. Do not blow or brush off contamination. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. For work with higher dust loads: Particle filter class P2 · Hand protection In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Nitrile-soaked cotton gloves (layer thickness approx. 0.15 mm) For activities using products containing cement, suitable protective gloves have been identified (GISCODES ZP1). Suitable are, for example Ampri: SolidSafety Cut 081101 / SolidSafety Tough 081201 / SolidSafetyTough Dots 081202 Ansell: Flexitril L27 / Fleximax 27 or 35 / Hylite / Nitrotough N210 / Sol-Knit KCL: Sahara / Gobi / Nitex MAPA: Duo-Mix 405 / Enduro 328 / Stansolv AK 22 / Titanlite 397 / Titansuperlite UVEX: uvex Profi Ergo XG 20 / uvex phynomic pro The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · For the permanent contact in work areas without heightened risk of injury (e.g. Laboratory) gloves made of the following material are suitable: Nitrile rubber, NBR · Eye/face protection In case of dust formation or risk of splashing: safety goggles (Contd. on page 5) GB
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Trade name: CRISTALLFUGE-EPOX (C-Komp.) jasmin, pergamon, silbergrau, weiß (Contd. of page 4)
Tightly sealed safety glasses. · Body protection: Contaminated protection clothes must be cleaned carefully before reuse. · Skin protection Use greasy skin protection ointment for all uncovered parts of the body! *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Solid material. · Colour: According to product specification · Smell: Odourless · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range not apply · Flammability Not determined. · Lower and upper explosion limit · Lower: Not determined. · Upper: Not determined. · Flash point: Not applicable · Decomposition temperature: Not determined. · pH at 20 °C 9 (1%) · Viscosity: · Kinematic viscosity Not applicable. · dynamic: Not applicable. · Solubility · Water: miscible · Partition coefficient n-octanol/water (log value) Not determined. · Steam pressure: Not applicable. · Density and/or relative density · Density bulk density · Relative density Not determined. · Settled apparent density 1.33 kg/dm³ · Vapour density Not applicable. · 9.2 Other information · Appearance: · Form: Powder · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Change in condition · Evaporation rate Not applicable. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids
Void Void Void Void Void Void Void Void Void (Contd. on page 6) GB
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Trade name: CRISTALLFUGE-EPOX (C-Komp.) jasmin, pergamon, silbergrau, weiß (Contd. of page 5)
· Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 13463-67-7 titanium dioxide Oral LD50 >5,000 mg/kg (rats) Dermal LD50 >10,000 mg/kg (rabbit) Inhalative LC50/4 h 6.8 mg/l (rats) 123-26-2 N,N'-ethane-1,2-diylbis(12-hydroxyoctadecan-1-amide) Oral LD50 >2,000 mg/kg (rats) Inhalative LC50/4 h 5.05 mg/l (rats) · Primary irritant effect: No irritant action known. · Skin corrosion/irritation The product has an irritate-effect. · Serious eye damage/irritation Irritate-effect is possible. · Carcinogenicity Suspected of causing cancer. Route of exposure: Inhalation. · STOT-repeated exposure May cause damage to the lung through prolonged or repeated exposure. Route of exposure: Inhalation. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 13463-67-7 titanium dioxide LC 0 48 mg/l (Leuciscus idus) EC0 30 mg/l (Daphnia magna) (Contd. on page 7) GB
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Trade name: CRISTALLFUGE-EPOX (C-Komp.) jasmin, pergamon, silbergrau, weiß (Contd. of page 6)
24 mg/l (Pseudomonas flourescens) 123-26-2 N,N'-ethane-1,2-diylbis(12-hydroxyoctadecan-1-amide) EC 50 >100 mg/kg /72h (algae toxicity) EL 50 >10 mg/l /48h (Daphnia magna) LL50 >10 mg/l /96h (rainbow trout) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties For information on endocrine disrupting properties see section 11. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards:
Not applicable.
· 14.6 Special precautions for user
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · UN "Model Regulation":
Void GB
(Contd. on page 8)
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Trade name: CRISTALLFUGE-EPOX (C-Komp.) jasmin, pergamon, silbergrau, weiß (Contd. of page 7)
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Poisons Act · Regulated explosives precursors None of the ingredients is listed. · Regulated poisons None of the ingredients is listed. · Reportable explosives precursors None of the ingredients is listed. · Reportable poisons None of the ingredients is listed. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. · Department issuing data specification sheet: Environment protection department. · Contact: Environment protection department. Mr. Guido Herfort · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Skin Sens. 1B: Skin sensitisation – Category 1B Carc. 2: Carcinogenicity – Category 2 STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB