57.0.19
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Safety data sheet according to 1907/2006/EC, Article 31 Printing date 10.11.2023
Version number 1
Revision: 10.11.2023
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-V2260 (A-Komp.) · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the mixture Sealing · Uses advised against Applications not mentioned above are not recommended. · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 email: info@schomburg.de web: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-Mail: SDB@schomburg.de · 1.4 Emergency telephone number: Poison Control Berlin (24 hrs.) German & English Tel: ++49 (0)30/30686700 SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 environment Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.
Skin Sens. 1
H317 May cause an allergic skin reaction.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS07, GHS09 · Signal word Warning (Contd. on page 2) GB
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Trade name: ASODUR-V2260 (A-Komp.) (Contd. of page 1)
· Hazard-determining components of labelling: Hexanedioic acid, polymer with 2-oxiranylmethylneodecanoate · Hazard statements H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects. · Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves. P302+P352 IF ON SKIN: Wash with plenty of water. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: formulated polyol component · Dangerous components: CAS: 716336-43-5
Hexanedioic acid, polymer with 2oxiranylmethylneodecanoate Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Sens. 1B, H317
2.5-10% Skin
CAS: 72623-86-0 Lubricating oils (petroleum), C15-30, hydrotreated neutral oil- 2.5-10% EINECS: 276-737-9 based Index number: 649-482-00-X Asp. Tox. 1, H304 · Additional information For the wording of the listed hazard phrases refer to section 16. SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. · After skin contact Affected skin must instantly rinse with water and a mild cleaning agent. · After eye contact Rinse opened eye for several minutes under running water. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. GB
(Contd. on page 3)
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Trade name: ASODUR-V2260 (A-Komp.) (Contd. of page 2)
SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents Carbon dioxide (CO2). Foam. Dry powder. · 5.2 Special hazards arising from the substance or mixture Not flammable · 5.3 Advice for firefighters · Protective equipment: Put on breathing apparatus. Wear full protective suit. · Additional information Collect contaminated fire fighting water separately. It must not enter drains. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Do not breath in vapour. Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep away from children. · Information about protection against explosions and fires: Standard fire prevention measures · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store only in the original container. Keep container tightly closed in a dry, well-ventilated place. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Recommended storage temperature 10 - 30°C · 7.3 Specific end use(s) Further information: Information system of the Berufsgenossenschaft der Bauwirtsschaft at www.gisbau.de Leaflet M044, Production and processing of polyurethanes/isocyanates. (Ed.: Berufsgenossenschaft of the Chemical Industry) SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. (Contd. on page 4) GB
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Trade name: ASODUR-V2260 (A-Komp.) (Contd. of page 3)
· Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: When properly used no respiratory protection needed · Hand protection Do not reuse one-way-gloves In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves When handling chemical substances, only chemical protective gloves with a CE mark including a four-digit test number may be worn. The design of chemical protective gloves must be selected depending on the concentration and quantity of hazardous substances in the workplace. It is recommended It is recommended to clarify the chemical resistance of the above-mentioned protective gloves for special applications with the glove manufacturer. Recommendation according to EN 374: For short-term work or as splash protection: Gloves made of butyl rubber/nitrile rubber (0.4 mm), Change and dispose of contaminated gloves immediately. Change and dispose of contaminated gloves immediately. For permanent product contact: Viton gloves (0.4 mm) Penetration time >30 min. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye/face protection Safety glasses recommended during refilling. · Body protection: long-sleeved clothing SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Fluid · Colour: White · Smell: weak · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range Not determined · Flammability Not applicable. · Lower and upper explosion limit · Lower: Not determined. (Contd. on page 5) GB
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Trade name: ASODUR-V2260 (A-Komp.) (Contd. of page 4)
· Upper: · Flash point: · Decomposition temperature: · pH at 20 °C · Viscosity: · Kinematic viscosity · dynamic at 20 °C: · Solubility · Water: · Partition coefficient n-octanol/water (log value) · Steam pressure: · Density and/or relative density · Density at 20 °C · Relative density · Vapour density
Not determined. >100 °C Not determined. 8 Not determined. 50-80 mPas miscible Not determined. Not determined. 1.03 g/cm³ Not determined. Not determined.
· 9.2 Other information · Appearance: · Form: Liquid · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability Stable under normal storage conditions. · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions No dangerous reactions known · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. (Contd. on page 6) GB
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Trade name: ASODUR-V2260 (A-Komp.) (Contd. of page 5)
· 10.6 Hazardous decomposition products: No dangerous decomposition products known SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: Toxicological examinations at chemical indentical products have produce this conclusion 72623-86-0 Lubricating oils (petroleum), C15-30, hydrotreated neutral oil-derived; Baseoil unspecified oral / LD 50mg/kg = >5000 / Rat (OECD 401) / [ECHA Dossier] dermal / LD 50mg/kg = >2000 / rat (OECD 401) / [ECHA Dossier] inhalative (4h) dust/mist/ LD 50mg/kg = >5,53 / rat (OECD 401) / [ECHA Dossier] · Primary irritant effect: No irritant action known. · Serious eye damage/irritation Irritate-effect is possible. · Respiratory or skin sensitisation May cause an allergic skin reaction. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: Very toxic to aquatic organisms. Very toxic to aquatic life with long lasting effects. · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: The substances in the mixture do not fulfil the PBT/vPvB criteria according to UK REACH, Annex XIII. The product has not been tested. · vPvB: The substances in the mixture do not fulfil the PBT/vPvB criteria according to UK REACH, Annex XIII. The product has not been tested. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water hazard class 2 (Self-assessment): hazardous for water. Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. (Contd. on page 7) GB
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Trade name: ASODUR-V2260 (A-Komp.) (Contd. of page 6)
· Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR · IMDG
· IATA
UN3082 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Hexanedioic acid, polymer with 2-oxiranylmethylneodecanoate) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Hexanedioic acid, polymer with 2oxiranylmethylneodecanoate), MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Hexanedioic acid, polymer with 2oxiranylmethylneodecanoate)
· 14.3 Transport hazard class(es) · ADR, IMDG, IATA
· Class · Label
9 Miscellaneous dangerous substances and articles. 9
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards: · Marine pollutant: · Special marking (ADR): · Special marking (IATA):
Symbol (fish and tree) Symbol (fish and tree) Symbol (fish and tree)
· 14.6 Special precautions for user · Kemler Number: · EMS Number: · Stowage Category
Warning: Miscellaneous dangerous substances and articles. 90 F-A,S-F A
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category
5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml 3 (Contd. on page 8) GB
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Trade name: ASODUR-V2260 (A-Komp.) (Contd. of page 7)
· IMDG · Limited quantities (LQ) · Excepted quantities (EQ)
· UN "Model Regulation":
5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (HEXANEDIOIC ACID, POLYMER WITH 2OXIRANYLMETHYLNEODECANOATE), 9, III
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · Seveso category E1 Hazardous to the Aquatic Environment · Qualifying quantity (tonnes) for the application of lower-tier requirements 100 t · Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H304 May be fatal if swallowed and enters airways. H317 May cause an allergic skin reaction. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. · Department issuing data specification sheet: Environment protection department. · Contact: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Skin Sens. 1: Skin sensitisation – Category 1 Skin Sens. 1B: Skin sensitisation – Category 1B Asp. Tox. 1: Aspiration hazard – Category 1 Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 GB