60.0.13
Page 1/11
Safety data sheet according to UK REACH Printing date 13.12.2024 *
Version number 22 (replaces version 21)
Revision: 13.12.2024
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: ASODUR-SG3 (B-Komp.) · UFI: RGV9-EKE5-R00V-0QU4 · 1.2 Relevant identified uses of the substance or mixture and uses advised against · Sector of Use SU19 Building and construction work · Application of the substance / the mixture Epoxy coating · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de · 1.4 Emergency telephone number: Poison centre Berlin (24 hours) German & English Tel: ++49 (0)30/30686700
*
SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS08 health hazard Repr. 2
H361f Suspected of damaging fertility. GHS05 corrosion
Skin Corr. 1B Eye Dam. 1
H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage.
GHS09 environment Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects. (Contd. on page 2) GB
Page 2/11
Safety data sheet according to UK REACH Printing date 13.12.2024
Trade name: ASODUR-SG3 (B-Komp.) (Contd. of page 1)
GHS07 Skin Sens. 1
H317 May cause an allergic skin reaction.
· 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the GB CLP regulation. · Hazard pictograms GHS05, GHS07, GHS08, GHS09 · Signal word Danger · Hazard-determining components of labelling: Tall-oil fatty acids oligomeric reaction products with triethylenetriamine and glycidyl tolyl ether m-phenylenebis(methylamine) 4-tert-butylphenol N'-(3-aminopropyl)-N,N-dimethylpropane-1,3-diamine 2,2,4-trimethylhexan-1,6-diamine · Hazard statements H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H361f Suspected of damaging fertility. H410 Very toxic to aquatic life with long lasting effects. · Precautionary statements P260 Do not breathe dusts or mists. P273 Avoid release to the environment. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/ international regulations. · Additional information: EUH071 Corrosive to the respiratory tract. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. *
SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: Modified cycloaliphatic Polyamine · Dangerous components: CAS: 1628940-03-3
Tall-oil fatty acids oligomeric reaction products with triethylenetriamine and glycidyl tolyl ether Eye Dam. 1, H318; Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Skin Irrit. 2, H315; Skin Sens. 1, H317
CAS: 98-54-4 4-tert-butylphenol EINECS: 202-679-0 Repr. 2, H361f; Eye Dam. 1, H318; Index number: 604-090-00-8 1, H410; Skin Irrit. 2, H315 CAS: 1477-55-0 EINECS: 216-032-5
50-100%
10-25% Aquatic Chronic
m-phenylenebis(methylamine) 2.5-10% Skin Corr. 1B, H314; Eye Dam. 1, H318; Acute Tox. 4, H302; Acute Tox. 4, H332; Skin Sens. 1B, H317; Aquatic Chronic 3, H412, EUH071 (Contd. on page 3) GB
Page 3/11
Trade name: ASODUR-SG3 (B-Komp.) (Contd. of page 2)
CAS: 90-72-2 2,4,6-tris(dimethylaminomethyl)phenol EINECS: 202-013-9 Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Irrit. 2, Index number: 603-069-00-0 H315; Eye Irrit. 2, H319
2.5-10%
CAS: 10563-29-8 EINECS: 234-148-4
N'-(3-aminopropyl)-N,N-dimethylpropane-1,3-diamine 2.5-10% Skin Corr. 1B, H314; Eye Dam. 1, H318; Acute Tox. 4, H302; Skin Sens. 1A, H317
CAS: 25513-64-8 EINECS: 247-063-2
2,2,4-trimethylhexan-1,6-diamine 2.5-10% Skin Corr. 1A, H314; Eye Dam. 1, H318; Acute Tox. 4, H302; Skin Sens. 1, H317; Aquatic Chronic 3, H412
· SVHC 98-54-4 4-tert-butylphenol · Additional information For the wording of the listed hazard phrases refer to section 16. *
SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Instantly remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. In case of unconsciousness bring patient into stable side position for transport. Supply fresh air and call for doctor for safety reasons. · After skin contact Don't use solvents to clean the skin. After cauterisation, rinse the skin for 15 minutes under cold runnig water. Instantly wash with water and soap and rinse thoroughly. Change immediately contaminated clothes. · After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. · After swallowing No administration of home remedies (milk, alcohol, oil, etc.). Drink copious amounts of water and provide fresh air. Instantly call for doctor. Do not induce vomiting; instantly call for medical help. Instantly call for doctor. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet. · 5.2 Special hazards arising from the substance or mixture Formation of poisonous gases during heating or in fires. (Contd. on page 4) GB
Page 4/11
Trade name: ASODUR-SG3 (B-Komp.) (Contd. of page 3)
· 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Keep away from ignition sources Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralising agent. Ensure adequate ventilation. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Ensure good ventilation/extraction at the workplace. Prevent formation of aerosols. Keep out of the reach of children · Information about protection against explosions and fires: No special measures required. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: No special requirements. · Information about storage in one common storage facility: Store away from foodstuffs. Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: Keep container tightly sealed. Store in a locked cabinet and out of the reach of children. · 7.3 Specific end use(s) No further relevant information available. *
SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists that were valid during the compilation were used as basis. · 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. (Contd. on page 5) GB
Page 5/11
Trade name: ASODUR-SG3 (B-Komp.) (Contd. of page 4)
· Individual protection measures, such as personal protective equipment · General protective and hygienic measures Wash hands during breaks and at the end of the work. The usual precautionary measures should be adhered to in handling the chemicals. Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Avoid contact with the eyes and skin. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. Gas filter A (brown) in unclear conditions or in confined, unventilated spaces. Wear combination filter A2-P2 (brown/white) when spraying. · Hand protection Hand Protection: Nitril-rubber-latex-gloves. In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Nitril-rubber-latex-gloves II R: Thickness 0,5mm; Penetration time 480 min Nitrile rubber II R : thickness 0.425mm; breakthrough time 480 min The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Not suitable are gloves made of the following materials: Leather gloves Strong gloves · Eye/face protection Tightly sealed safety glasses. Suitable safety goggles in accordance with DIN EN 166. In case of splashing use protecting basket-glasses. · Body protection: Acid resistant protective clothing Alkaline resistant protective clothing Apron Protective work clothing. Use an Overall of heavy cotton or non-returnable Tyvek/Saranex 23 P vleece. Contaminated protection clothes must be cleaned carefully before reuse. *
SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Fluid · Colour: Ember coloured · Smell: Amine-like · Odour threshold: Not determined. · Melting point/freezing point: Not determined (Contd. on page 6) GB
Page 6/11
Trade name: ASODUR-SG3 (B-Komp.) (Contd. of page 5)
· Boiling point or initial boiling point and boiling range · Flammability · Lower and upper explosion limit · Lower: · Upper: · Flash point: · Decomposition temperature: · pH · Viscosity: · Kinematic viscosity · dynamic at 20 °C: · Solubility · Water: · Partition coefficient n-octanol/water (log value) · Steam pressure: · Density and/or relative density · Density at 20 °C · Relative density · Vapour density
Not determined Not applicable. Not determined. Not determined. Not applicable Not determined. Mixture is non-soluble (in water). Not determined. 1,300 mPas Not miscible or difficult to mix Not determined. Not determined. 1 g/cm³ Not determined. Not determined.
· 9.2 Other information · Appearance: · Form: Fluid · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Solvent separation test · Solids content: 0.0 % · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void GB
(Contd. on page 7)
Page 7/11
Trade name: ASODUR-SG3 (B-Komp.) (Contd. of page 6)
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised Develops corrosive gases / fumes · 10.4 Conditions to avoid No further relevant information available. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: Corrosive gases/vapours *
SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: 1628940-03-3 Tall-oil fatty acids oligomeric reaction products with triethylenetriamine and glycidyl tolyl ether Oral LD50 >2,000 mg/kg (rats) LD50 >2,000 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rats) 98-54-4 4-tert-butylphenol Oral LD50 2,951 mg/kg (rats) Dermal LD50 2,288 mg/kg (rabbit) 1477-55-0 m-phenylenebis(methylamine) Oral LD50 930 mg/kg (rats) (OECD 401) Dermal LD50 >3,100 mg/kg (rabbit) (OECD 402) Inhalative LC50 2.4 mg/l (not defined) LC50/4 h 1.34 mg/l (rats) (OECD 403) 90-72-2 2,4,6-tris(dimethylaminomethyl)phenol Oral LD50 2,169 mg/kg (rats) (OECD 401) Dermal LD50 1,280 mg/kg (rats) 10563-29-8 N'-(3-aminopropyl)-N,N-dimethylpropane-1,3-diamine Oral LD50 1,670 mg/kg (rats) Dermal LD50 1,310 mg/kg (rats) 25513-64-8 2,2,4-trimethylhexan-1,6-diamine Oral LD50 910 mg/kg (rats) EC/LC50 (24h) 31.5 mg/l (Daphnia magna) 919-30-2 3-aminopropyltriethoxysilane Oral LD50 1,490 mg/kg (rats) (EPA Method) Dermal LD50 >2,000 mg/kg (Kan) (EPA Method) · Specific symptoms in biological assay: 919-30-2 3-aminopropyltriethoxysilane NOAEL 200 mg/kg (rats) (OECD TG 408) · Primary irritant effect: · Skin corrosion/irritation Causes severe skin burns and eye damage. · Serious eye damage/irritation Causes serious eye damage. (Contd. on page 8) GB
Page 8/11
Trade name: ASODUR-SG3 (B-Komp.) (Contd. of page 7)
· Respiratory or skin sensitisation May cause an allergic skin reaction. · Reproductive toxicity Suspected of damaging fertility. · 11.2 Information on other hazards · Endocrine disrupting properties 98-54-4 4-tert-butylphenol: List I SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 98-54-4 4-tert-butylphenol LC50/96h >1 mg/l (rainbow trout) (OECD 203) EC50 (48h) (static) 4.8 mg/l (Daphnia magna) (OECD 202) ERC50 (static) 14 mg/l /72h (Selenastrum capricornutum) (OECD 201) NOEC 0.73 mg/l /21d (Daphnia magna) (OECD 211) 0.01 mg/l /128d (Pimephales promelas) (OECD 210) 1477-55-0 m-phenylenebis(methylamine) LC50/96h 87.6 mg/l (fish toxicity) >100 mg/l (for) >100 mg/l (Danio rerio) EC50 (48h) 15.2 mg/l (Daphnia magna) EC/LC50 (72h) 20.3 mg/l (algae toxicity) 90-72-2 2,4,6-tris(dimethylaminomethyl)phenol LC50/96h (static) 175 mg/l (Karpfen (Cyprinus carpio)) EC50 (48h) (static) 718 mg/l (Daphnia (acute) toxicity) ERC50 84 mg/l /72h (Selenastrum capricornutum) (OECD 201) NOEC (static) 6.25 mg/l /72h (Grünalge (Scenedesmus subspicatus)) (OECD 201) 25513-64-8 2,2,4-trimethylhexan-1,6-diamine LC50 (48h) 174 mg/l (Leuciscus idus) EC/LC50 (17h) 89 mg/l (Pseudomas putida) ERC50 43.5 mg/l (Scenedesmus subspicatus) 919-30-2 3-aminopropyltriethoxysilane LC 0 >934 mg/l /(96h) (Brachydanio rerio) (OECD TG 203) EC10 13 mg/l /(5.75h) (Pseudomas putida) (Bringmann & Kühn, 10, 87-98 (1977)) EC50 (48h) 331 mg/l (Daphnia magna) (OECD TG 202) EC/LC50 (72h) >1,000 mg/l (Desmodesmus subspicatus) (OECD TG 201) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties For information on endocrine disrupting properties see section 11. · 12.7 Other adverse effects · Additional ecological information: · General notes: Water danger class 3 (Self-assessment): extremely hazardous for water. Do not allow product to reach ground water, water bodies or sewage system, even in small quantities. (Contd. on page 9) GB
Page 9/11
Trade name: ASODUR-SG3 (B-Komp.) (Contd. of page 8)
Must not reach sewage water or drainage ditch undiluted or unneutralised. Danger to drinking water if even extremely small quantities leak into soil. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, IMDG, IATA · 14.2 UN proper shipping name · ADR · IMDG, IATA
UN2735 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (mphenylenebis(methylamine), 4-tert-butylphenol), ENVIRONMENTALLY HAZARDOUS AMINES, LIQUID, CORROSIVE, N.O.S. (mphenylenebis(methylamine), 4-tert-butylphenol)
· 14.3 Transport hazard class(es) · ADR, IMDG
· Class · Label
8 Corrosive substances. 8
· IATA
· 14.4 Packing group · ADR, IMDG, IATA
III
· 14.5 Environmental hazards:
· Special marking (ADR):
Product contains environmentally hazardous substances: 4-tert-butylphenol Yes Symbol (fish and tree) Symbol (fish and tree)
· 14.6 Special precautions for user · Kemler Number: · EMS Number: · Segregation groups · Stowage Category
Warning: Corrosive substances. 80 F-A,S-B (SGG18) Alkalis A
· Marine pollutant:
(Contd. on page 10) GB
Page 10/11
Trade name: ASODUR-SG3 (B-Komp.) (Contd. of page 9)
· Segregation Code
SG35 Stow "separated from" SGG1-acids
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · Transport/Additional information: · ADR · Limited quantities (LQ) · Excepted quantities (EQ) · Transport category · IMDG · Limited quantities (LQ) · Excepted quantities (EQ)
· UN "Model Regulation":
5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml 3 5L Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (M-PHENYLENEBIS(METHYLAMINE), 4-TERTBUTYLPHENOL), 8, III, ENVIRONMENTALLY HAZARDOUS
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Poisons Act · Regulated explosives precursors None of the ingredients is listed. · Regulated poisons None of the ingredients is listed. · Reportable explosives precursors None of the ingredients is listed. · Reportable poisons None of the ingredients is listed. · Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · Seveso category E1 Hazardous to the Aquatic Environment · Qualifying quantity (tonnes) for the application of lower-tier requirements 100 t · Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t · National regulations · Substances of very high concern (SVHC) according to UK REACH 98-54-4 4-tert-butylphenol · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. (Contd. on page 11) GB
Page 11/11
Trade name: ASODUR-SG3 (B-Komp.) (Contd. of page 10)
H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H361f Suspected of damaging fertility. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. EUH071 Corrosive to the respiratory tract. · Department issuing data specification sheet: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 4: Acute toxicity – Category 4 Skin Corr. 1A: Skin corrosion/irritation – Category 1A Skin Corr. 1B: Skin corrosion/irritation – Category 1B Skin Irrit. 2: Skin corrosion/irritation – Category 2 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Eye Irrit. 2: Serious eye damage/eye irritation – Category 2 Skin Sens. 1: Skin sensitisation – Category 1 Skin Sens. 1A: Skin sensitisation – Category 1A Skin Sens. 1B: Skin sensitisation – Category 1B Repr. 2: Reproductive toxicity – Category 2 Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
· * Data compared to the previous version altered. GB