60.0.21
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Safety data sheet according to UK REACH Printing date 24.01.2025 *
Version number 21 (replaces version 20)
Revision: 24.01.2025
SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: AQUAFIN-i380 · 1.2 Relevant identified uses of the substance or mixture and uses advised against · Sector of Use SU19 Building and construction work · Application of the substance / the mixture Surface protection · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: SCHOMBURG GmbH & Co. KG Aquafinstr. 2-8 D-32760 Detmold Detmold, Germany ---------------------------------------------Tel: ++49 (0)5231/953-00 Fax: ++49 (0)5231/953-123 Internet: www.schomburg.de · Informing department: Department: Environment and Safety ************************************ If you have any questions about the Environment and Safety Department, please contact our department. e-mail: SDB@schomburg.de · 1.4 Emergency telephone number: Poison centre Berlin (24 hours) German & English Tel: ++49 (0)30/30686700 SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 The product is not classified, according to the GB CLP regulation. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 Void · Hazard pictograms Void · Signal word Void · Hazard statements Void · Additional information: EUH208 Contains reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1). May produce an allergic reaction. EUH210 Safety data sheet available on request. · 2.3 Other hazards Inhalation of aerosol mists can be harmful to health. Product hydrolyses to form ethanol (CAS No. 64-17-5). Ethanol is classified with regard to physical and health hazards. The rate of hydrolysis and thus the relevance for the hazard potential of the product are highly dependent on the specific conditions. · Results of PBT and vPvB assessment · PBT: Not applicable. (Contd. on page 2) GB
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Safety data sheet according to UK REACH Printing date 24.01.2025
Trade name: AQUAFIN-i380 (Contd. of page 1)
· vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Mixtures · Description: alkoxisilane · Dangerous components: CAS: 55965-84-9 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC <0.0015% EC number: 611-341-5 no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. Index number: 613-167-00-5 220-239-6] (3:1) Acute Tox. 3, H301; Acute Tox. 2, H310; Acute Tox. 2, Skin Corr. 1C, H314; Eye Dam. 1, H318; H330; Aquatic Acute 1, H400 (M=100); Aquatic Chronic 1, H410 (M=100); Skin Sens. 1A, H317, EUH071 Specific concentration limits: Skin Corr. 1C; H314: C ≥ 0.6 % Skin Irrit. 2; H315: 0.06 % ≤ C < 0.6 % Eye Dam. 1; H318: C ≥ 0.6 % Eye Irrit. 2; H319: 0.06 % ≤ C < 0.6 % Skin Sens. 1A; H317: C ≥ 0.0015 % · Additional information For the wording of the listed hazard phrases refer to section 16. SECTION 4: First aid measures · 4.1 Description of first aid measures · General information Personal protection for the First Aider. It is possible to choke in case of vomiting in unconsciousness. Bring unconscious persons into a stable position on side. Keep the respiratory tract free (remove dentures and vomiting). Check the pulse. In case of heart failure you have to make a cardiac massage. In case of stoppage of breathing: artificial respiration. Take up a doctor immediately! · After inhalation Supply fresh air or oxygen; call for doctor. · After eye contact Rinse opened eye for several minutes under running water. · After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor. Show the packaging or the label to the doctor. · 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. Use fire fighting measures that suit the environment. · 5.2 Special hazards arising from the substance or mixture Hazardous vapours may be generated by surrounding fire. Exposure to combustion products can be a health hazard! Hazardous fire products: toxic and very toxic fumes. (Contd. on page 3) GB
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Trade name: AQUAFIN-i380 (Contd. of page 2)
· 5.3 Advice for firefighters · Protective equipment: Wear self-contained breathing apparatus. · Additional information Follow the emergency-plan. Burst- and explosion-danger by increasing pressure. In case of fire chill the container with water spray. SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Bring persons out of danger. Wear protective equipment. Keep unprotected persons away. · 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies. Inform respective authorities in case product reaches water or sewage system. · 6.3 Methods and material for containment and cleaning up: Dispose of the material collected according to regulations. · 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep out of the reach of children · Information about protection against explosions and fires: Fumes can combine with air to form an explosive mixture. · Handling Always stir well before use. · 7.2 Conditions for safe storage, including any incompatibilities · Storage · Requirements to be met by storerooms and containers: Store at temperatures between 5 and 35 °C. Containers must be stored thick closed at a cool, ventilated place. Store in a dry place. · Information about storage in one common storage facility: Please follow the rules of the VCI-Storage-Concept for chemicals. · Further information about storage conditions: None. · 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection · 8.1 Control parameters · Components with critical values that require monitoring at the workplace: Air limit values at the workplace (TRGS 900): Substance: Ethanol Type: AGW mg/m3: 380.0 ppm: 200.0 Ethanol: Exceedance factor 4(II); Notes DFG and Y (= there is no need to fear a risk of fruit damage if the occupational exposure limit value and the biological limit value (BGW) are complied with) (as at: June 2018). · Additional information: The lists that were valid during the compilation were used as basis. (Contd. on page 4) GB
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Trade name: AQUAFIN-i380 (Contd. of page 3)
· 8.2 Exposure controls · Appropriate engineering controls It must be possible to wash the skin in the working area. Eye-wash bottle must be available. · Individual protection measures, such as personal protective equipment · General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Do not eat, drink or smoke while working. Use skin protection cream for preventive skin protection. Be sure to clean skin thoroughly after work and before breaks. · Breathing equipment: Use breathing protection only when aerosol or mist is formed. · Hand protection In case of wearing synthetic protective gloves use cotton-gloves as underwear. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves Gloves made of: Natural latex, polychloroprene, nitrile rubber. (Chemical protection gloves of category 3, recognisable by the CE mark with four-digit test number). The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Not suitable are gloves made of the following materials: Leather gloves Strong gloves · Eye/face protection Suitable safety goggles in accordance with DIN EN 166. · Body protection: Protective work clothing. SECTION 9: Physical and chemical properties · 9.1 Information on basic physical and chemical properties · General Information · Physical state Liquid · Colour: Yellowish · Smell: Weak, characteristic · Odour threshold: Not determined. · Melting point/freezing point: Not determined · Boiling point or initial boiling point and boiling range 100 °C · Flammability Not applicable. · Lower and upper explosion limit · Lower: 3.5 Vol % (Ethanol CAS 64-17-5, 64-17-5 ethanol) · Upper: 15 Vol % (Ethanol CAS 64-17-5, 64-17-5 ethanol) · Flash point: 64 °C · Auto-ignition temperature: 265 °C · Decomposition temperature: Not determined. · pH at 20 °C 4.5-7 · Viscosity: · Kinematic viscosity at 20 °C 0 s (DIN 53211/4) · dynamic: Not determined. (Contd. on page 5) GB
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Trade name: AQUAFIN-i380 (Contd. of page 4)
· Solubility · Water: · Partition coefficient n-octanol/water (log value) · Steam pressure at 20 °C: · Density and/or relative density · Density at 20 °C · Relative density · Vapour density
miscible Not determined. 23 hPa 0.9 g/cm³ 0.9 (25 °C; 1013 hPa) Not determined.
· 9.2 Other information · Appearance: · Form: Pasty · Important information on protection of health and environment, and on safety. · Self-inflammability: Product is not selfigniting. · Explosive properties: Product is not explosive. · Solvent separation test · Organic solvents: 0.0 % · Solids content: 0.0 % · Change in condition · Evaporation rate Not determined. · Information with regard to physical hazard classes · Explosives · Flammable gases · Aerosols · Oxidising gases · Gases under pressure · Flammable liquids · Flammable solids · Self-reactive substances and mixtures · Pyrophoric liquids · Pyrophoric solids · Self-heating substances and mixtures · Substances and mixtures, which emit flammable gases in contact with water · Oxidising liquids · Oxidising solids · Organic peroxides · Corrosive to metals · Desensitised explosives
Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void Void
SECTION 10: Stability and reactivity · 10.1 Reactivity No further relevant information available. · 10.2 Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · 10.3 Possibility of hazardous reactions Reacts with acids Reacts with alkali (lyes) · 10.4 Conditions to avoid Heat, open flames and miscellaneous sources of ignition. · 10.5 Incompatible materials: No further relevant information available. · 10.6 Hazardous decomposition products: By heating about 150°C in present of air, could be realase small amounts of formaldehyde. (Contd. on page 6) GB
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Trade name: AQUAFIN-i380 (Contd. of page 5)
Upon hydrolysation: Ethanol SECTION 11: Toxicological information · 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 · Acute toxicity Based on available data, the classification criteria are not met. · LD/LC50 values that are relevant for classification: Oral LD50 >2,000 mg/kg (rats) Dermal LD50 >2,000 mg/kg (rats) Inhalative LC50 >5.2 mg/l (rats) 55965-84-9 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) Oral LD50 64 mg/kg (rats) Dermal LD50 87.12 mg/kg (Kan) Inhalative LC50/4 h 0.33 mg/l (rats) · Primary irritant effect: No irritant action known. · Skin corrosion/irritation It is possible to irritate the skin. Based on available data, the classification criteria are not met. · Serious eye damage/irritation Irritate-effect is possible. Based on available data, the classification criteria are not met. · Respiratory or skin sensitisation Based on available data, the classification criteria are not met. · Germ cell mutagenicity Based on available data, the classification criteria are not met. · Carcinogenicity Based on available data, the classification criteria are not met. · Reproductive toxicity Based on available data, the classification criteria are not met. · STOT-single exposure Based on available data, the classification criteria are not met. · STOT-repeated exposure Based on available data, the classification criteria are not met. · Aspiration hazard Based on available data, the classification criteria are not met. · 11.2 Information on other hazards · Endocrine disrupting properties None of the ingredients is listed. SECTION 12: Ecological information · 12.1 Toxicity · Aquatic toxicity: 55965-84-9 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) LC50 (48h) 0.16 mg/l (Daphnia magna) (vgl OECD 202) LC50/96h 0.19 mg/l (rainbow trout) (vgl. OECD 203) ERC50 0.0052 mg/l (algae toxicity) (48h, OECD 201) NOEC 0.1 mg/l (Daphnia magna) (21 d) 0.05 mg/l (rainbow trout) (14 d) · 12.2 Persistence and degradability No further relevant information available. · 12.3 Bioaccumulative potential No further relevant information available. · 12.4 Mobility in soil No further relevant information available. · 12.5 Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · 12.6 Endocrine disrupting properties The product does not contain substances with endocrine disrupting properties. (Contd. on page 7) GB
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Trade name: AQUAFIN-i380 (Contd. of page 6)
· 12.7 Other adverse effects · Additional ecological information: · General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water. Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system. SECTION 13: Disposal considerations · 13.1 Waste treatment methods · Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. · Recommended cleaning agent: Water, if necessary with cleaning agent. SECTION 14: Transport information · 14.1 UN number or ID number · ADR, ADN, IMDG, IATA
Void
· 14.2 UN proper shipping name · ADR, ADN, IMDG, IATA
· 14.3 Transport hazard class(es) · ADR, ADN, IMDG, IATA · Class
· 14.4 Packing group · ADR, IMDG, IATA
· 14.5 Environmental hazards: · Marine pollutant:
No
· 14.6 Special precautions for user
Not applicable.
· 14.7 Maritime transport in bulk according to IMO instruments Not applicable. · UN "Model Regulation":
SECTION 15: Regulatory information · 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture · Poisons Act · Regulated explosives precursors None of the ingredients is listed. · Regulated poisons None of the ingredients is listed. · Reportable explosives precursors None of the ingredients is listed. · Reportable poisons None of the ingredients is listed. (Contd. on page 8) GB
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Trade name: AQUAFIN-i380 (Contd. of page 7)
· Directive 2012/18/EU · Named dangerous substances - ANNEX I None of the ingredients is listed. · 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. *
SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases H301 Toxic if swallowed. H310 Fatal in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H330 Fatal if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. EUH071 Corrosive to the respiratory tract. · Department issuing data specification sheet: Environment protection department. · Abbreviations and acronyms: ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative Acute Tox. 3: Acute toxicity – Category 3 Acute Tox. 2: Acute toxicity – Category 2 Skin Corr. 1C: Skin corrosion/irritation – Category 1C Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Skin Sens. 1A: Skin sensitisation – Category 1A Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
· * Data compared to the previous version altered. GB